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STRUCTURE, MAGNETISM AND MAGNETORESISTANCE OF ANNEALED Co/Cu DISCONTINUOUS MULTILAYERS

S.S. Yan , J.X. Lou , L. Zhang , R.Z. Zhang , Y.M. Zhang , Y.H. Liu , L.M. Mei and J. Huang(Department of Physics , Shandong University , Jinan 250100 , China)(Department of Environment Engineering , Shandong University , Jinan 250100 , China)

金属学报(英文版)

Co/Cu discontinuons multilayers were prepared by rf-sputtering method under high sputtering power and then annealed at various temperutures in a high vacuum. The structural, magnetic and transport properties were strongly influenced by the annealing temperature. The annealed samples obviously became discontinuous multilayers.A maximum magnetoresistance ratio of 5.6% was obtained under a relatively low saturation field of about 400 (103/4π)A/m at the optimum annealing temperature of 450℃. When the annealing temperature was increased, the resistivity decreased, and the coercive force and the saturation field increased. The magnetoresistance ratio also depended on the thickness of Co and Cu layers. The magnetic and transport properties were explained on the basis of the discontinuous multilayered structure.

关键词: discontinuous multilayers , null , null

Molecular Electrical Conductor Ni(C_3S_5)_2

Hong LEI (Dept. of Electronic Engineering , Shandong University , Jinan 250100 , China)Qi FANG and Minhua JIANG (Institute of Crystal Materials , Shandong University , Jinan 250100 , China)Yueming SUN (Dept. of Chemistry Southeast University Nanjing 210093 , Chi

材料科学技术（英）

The molecular based electrical conductor Ni(C3S5)2 has been prepared and its conductivity has been measured from room temperature down to 60 K. Above 167 K Ni(C3S5)2 exhibits a semiconductive behaviour, below this temperature it turns to exhibit metallic conductivity. Based on a tight-binding energy band calculation, an expression for the number of conducting electrons has been deduced. The calculated conducting activation energy is quite well in accordance with the measuring value.

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Photoelectrochemical Study of Passive Films on Sensitized Stainless Steel

Tianbao DU and Shenhao CHEN (Chemistry Dept. , Shandong University , Jinan 250100 , China)Maizhi YANG and Li CHEN (Chemistry Dept. , Peking University , Beijing 100871 , China)

材料科学技术（英）

Passive films formed on sensitized stainless steel in sulphuric acid solutions have been studied using photoefectrochemical techniques. The results of the photocurrent measurement indicate that the passive films on sensitized stainless steel are characterised with n-type or p-type semiconductor in different potential regions. The difference in the photoelectrochemical behaviour can be interpreted assuming that the passive film is an iron-chromium oxide solid solution associated with various hydration degrees of the Cr(Ⅲ) oxides at various potentials

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Magnetism and Its Dependence on Annealing Temperature for Sputtered Co/Cu Multilayers

Ruwei GAO , Yihua LIU , Shishen YAN Deheng ZHANG and Lin ZHANG(Dept. of Physics , Shandong University , Jinan 250100 , China)

材料科学技术（英）

Magnetism and its dependence on annealing temperature for r.f. sputtered Co/Cu multilayers have been investigated. It was found that the easy magnetization axes of the films are paralIel to the substrate and the magnetic properties of both as-sputtered and annealed multilayers are isotropic in the film plane. The coercive field Hc is 4.8 kA/m and the ratio of remanence-tosaturation magnetization Mi/M is about 0.73 for as-sputtered samples. Both Hc and Mr/Ms increase with increasing annealing temperatures, especially when annealing temperatures are higher than 400℃. These experimental results can be interpreted using the ferromagnetic exchange coupling and the pinning theory of the coercivity

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